Search

Patricia J. Kooyman

Professor Patricia J. Kooyman

SARChI chair Nanomaterials for Catalysis
Phone: Tel: 021 650 2732
Email: Patricia.kooyman@uct.ac.za

 

Overview/ Research interests

Synthesis and characterisation of nanoparticles and their application in catalysis.

Supported and unsupported metallic, oxidic and sulphidic catalysts. Zeolites and porous materials.

Fischer-Tropsch catalysis, reduction-oxidation catalysis, hydrocarbon processing, wax upgrading, hydrodesulphurisation, photocatalysis, electrocatalysis.

High resolution transmission electron microscopy and in situ transmission electron microscopy.

 

Education

MSc: Leiden University, The Netherlands

PhD: Delft University of Technology, The Netherlands

 

Experience

Post-Doc:

Shell Research, Amsterdam, The Netherlands

National Centre for HREM, Delft, The Netherlands

Faculty:

Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, The Netherlands

 

Major grants and Awards

Part of NIMIC consortium for the development of in situ TEM and SPM equipment

 

Publications

1988

1 T.L.F. Favre, P.J. Seijsener, P.J. Kooyman, A. Maltha, A.P. Zuur and V. Ponec,

Catal. Lett. 1 (1988) 457. Selective reduction of nitrobenzene to

nitrosobenzene on oxidic catalysts.

2 T.L.F. Favre, A. Maltha, P.J. Kooyman, A.P. Zuur and V. Ponec, Proceedings of

the XI Iberoamerican Catalysis Symposium, Guanajuato 1988, Vol II, p.

807. Selective reduction of nitrobenzene to nitrosobenzene catalysed by

manganese oxides.

 

1990

3 P.J. Kooyman, Appl. Catal. 66 (1990) N26. Meeting report: 13th annual

meeting of the British zeolite association.

1992

4 P.J. Kooyman, P. Van der Waal, P.A.J. Verdaasdonk, J.C. Jansen and H. Van

Bekkum, Catal. Lett. 13 (1992) 229. Titanium deposited from TiCl4 on

amorphous silica and silicalite-1 as catalyst in aromatic hydroxylation

reactions.

1993

5 J.A. Martens, Ph. Buskens, P.A. Jacobs, A. van der Pol, J.H.C. van Hooff, C.

Ferrini, H.W. Kouwenhoven, P.J. Kooyman and H. van Bekkum, Appl. Catal.

A: General 99 (1993) 71. Hydroxylation of phenol with hydrogen peroxide on

Euro-TS-1 catalyst.

6 P.J. Kooyman, J.C. Jansen and H. van Bekkum, Proceedings of the 9th

International Zeolite Conference, Montreal 1992, eds. R. von Ballmoos et

al., Butterworth-Heinemann, USA, 1993, p.505. Characterisation and

catalytic properties of titanium incorporated into zeolites and silicas from

titanium trifluoride.

1996

7 P.J. Kooyman, H.W. Zandbergen, K.R. Kloetstra and H. van Bekkum,

Proceedings of the 11th European Congress on Electron Microscopy

EUREM '96, Dublin, 1996, CD-rom. MCM-41: A transmission electron

microscopy study. Also in print: Volume 2, pp II-38 through II-39. Brussels

1998.

8 P.J. Kooyman, G.C.A. Luijkx, A. Arafat and H. van Bekkum, J. Molec. Catal.

111 (1996) 167. Microwave heating in the TS-1 catalysed oxyfunctionalisation

of n-hexane.

9 E.J. Creyghton, A.C.T. van Duin, J.C. Jansen, P.J. Kooyman, H.W. Zandbergen

and H. van Bekkum, J. Chem. Soc., Faraday Trans., 92 (1996) 4637.

Synthesis of Pt clusters in zeolite BEA: effect of reduction rate on cluster size

and location.

1997

10 P.J. Kooyman, P. van der Waal and H. van Bekkum, Zeolites 18 (1997) 50. Acid

dealumination of ZSM-5.

11 A. Lagerwaard, K.J. Volkers, D. Camelot, P.J. Kooyman and J. van Geel,

Proceedings of Workshop on the status of measurement techniques for

the identification of nuclear signatures, Geel (B) 1997, EUR 17312 EN p.

115. Preparation and characterization of micrometre size nuclear material

particles for analytical studies: a need for definition.

53 D. Camelot, K-L Chou, P.J. Kooyman, J.C.M. Marijnissen, B. Scarlett and J.P.

Borra, J. Aerosol Sci. 28 (1997) S529-S530. Production of various ceramic

powders using bipolar mixing.

1998

12 I. Peeters, A.W. Dernier van der Gon, M. Reijme, P.J. Kooyman, A.M. de Jong,

J. van Grondelle, H.H. Brongersma and R.A. van Santen, J. Catal. 173 (1998)

28. Structure-activity relationships in the oxidative ammonolysis of ethylene

over γ-Al2O3 supported molybdenum oxide catalysts.

13 F. Cot, P.J. Kooyman, A. Larbot and E. Prouzet, SSSC 117 (1998) 231.

(Mesoporous Molecular Sieves 1998, eds L. Bonneviot, F. Beland, C.

Danumah, S. Giasson and S. Kaliaguine) Improved synthesis of MSU-X silica

prepared by polyethylene oxide surfactants.

14 H.W. Zandbergen, P.J. Kooyman and A.D. van Langeveld, Electron

Microscopy 1998, proceedings ICEM 14, Cancun, Mexico, 31 August to 4

September 1998, Symposium W, Volume II, pp 491-492. Transfer systems

for insertion of specimens into electron microscopes under controlled

atmospheres.

15 H.R. Reinhoudt, A.D. van Langeveld, P.J. Kooyman, R.M. Stockmann, R. Prins,

H.W. Zandbergen and J.A. Moulijn, J. Catal. 179 (1998) 443-450. The

evolution of the surface species in NiW/Al2O3 catalysts in various stages of

sulfidation: A quasi in-situ high resolution electron microscopy investigation.

16 J.C. van der Waal, P.J. Kooyman, J.C. Jansen and H. van Bekkum,

Microporous and Mesoporous Materials 25 (1998) 43-57. Synthesis and

characterisation of aluminium-free zeolite titanium beta using

di(cyclohexylmethyl)dimethylammonium as a new and selective template.

1999

17 M.J. Verhoef, P.J. Kooyman, J.A. Peters and H. van Bekkum, Microporous and

Mesoporous Materials 27 (1999) 365-371. A study on the stability of

MCM-41 supported heteropoly acids under liquid- and gas-phase

esterification conditions.

18 E. Prouzet, F. Cot, G. Nabias, A. Larbot, P.J. Kooyman and T.J. Pinnavaia,

Chem. Mater. 11 (1999) 1498-1503. Assembly of Mesoporous Silica

Molecular Sieves Based on Nonionic Ethoxylated Sorbitan Esters as Structure

Directors.

19 J.P. Borra, D. Camelot, K-L Chou, P.J. Kooyman, J.C.M. Marijnissen and B.

Scarlett, J. Aerosol Sci. 30 (1999) 945-958. Bipolar Coagulation for powder

production: Micro-mixing inside droplets.

20 P.J. Kooyman, J.G. Buglass, H.R. Reinhoudt, A.D. van Langeveld, H.W.

Zandbergen and J.A.R. van Veen, Europacat IV book of abstracts (1999)

466. Quasi in situ sequential sulphidation of CoMo/Al2O3 studied using High

Resolution Electron Microscopy.

_3

21 J.C. Jansen, Z. Shan, L. Marchese, P.J. Kooyman and Th. Maschmeyer,

Europacat IV book of abstracts (1999) 127. TUD-1, a new generation of

ultrastable silicas with three-dimensionally connected meso- and micropore

networks.

22 L. Simon, J.G. van Ommen, P.J. Kooyman, A. Jentys and J.A. Lercher, DMKG

Tagungsbericht 9903, conference "The future role of aromatics in refining

and petrochemistry', Erlangen, Germany, October 13-15, 1999, pp

177-184. Sulphur tolerance of alkali exchanged zeolites for benzene

hydrogenation.

23 T. Mallat, S. Frauchiger, P.J. Kooyman, M. Schürch and A. Baiker. Catal. Lett.

63 (1999) 121-126. Restructuring during pretreatment of platinum/alumina

for enantioselective hydrogenation.

2000

24 R.J.H. Grisel, P.J. Kooyman and B.E. Nieuwenhuys. J. Catal. 191 (2000)

430-437. Influence of the preparation of Au/Al2O3 on the CH4 oxidation

activity.

25 P.J. Kooyman, M.J. Verhoef and E. Prouzet, Proceedings Nanoporous

Materials II, SSSC 129 (2000) 535-542. Banff, Alberta, Canada, May 25-30,

2000. Eds. A. Sayari, M. Jaroniec, T. Pinnavaia. Transmission Electron

Microscopy – an indispensable tool for the characterisation of M41S-type

materials.

26 C. Boissière, A. Larbot, A. van der Lee, P.J. Kooyman and E. Prouzet, Chem.

Mater. 12 (2000) 2902-2913. A new synthesis of mesoporous MSU-X silica

controlled by a two-step pathway.

27 E. Toukoniitty, P. Mäki-Arvela, A.N. Villela, A. Kalantar-Neyestanaki, T. Salmi,

R. Leino, R. Sjöholm, E. Laine, J. Väyrynen, T. Ollonqvist, and P.J.

Kooyman, Catal. Today 60 (2000) 175-184. The effect of oxygen and the

reduction temperature of the Pt/Al2O3 catalyst in enantioselective

hydrogenation of 1-phenyl-1,2-propanedione

28 H.R. Reinhoudt, E. Crezee, A.D. van Langeveld, P.J. Kooyman, J.A.R. van

Veen and J.A. Moulijn, J. Catal. 196 (2000) 315-329. Characterization of the

active phase in NiW/γ-Al2O3 catalysts in various stages of sulfidation with

FTIR(NO) and XPS.

29 F. Devred, P.J. Kooyman and H.W. Zandbergen, Jaarboek 2000 Nederlandse

Vereniging voor Microscopie, (2000) p. 52-53. A TEM/HREM study of

Raney-type catalysts.

91 R.D. Vis, A. Mwowiec, P.J. Kooyman and D. Heymann, Meteoritics and

planetary science 35 (2000) A165. Carbon nanobottle carriers of planetary

noble gases in Meteorites.

2001

30 F. Devred, P.J. Kooyman and H.W. Zandbergen, Proceedings NCCC II,

Noordwijkerhout, The Netherlands, March 5-7, 2001 p. 234. A TEM/

HREM study of Raney-type catalysts.

31 E.J.M. Hensen, P.J. Kooyman, Y. van der Meer, A.M. van der Kraan, V.H.J. de

Beer, J.A.R. van Veen, R.A. van Santen, J. Catal. 199 (2001) 224-235. The

relation between morphology and hydrotreating activity for supported MoS2

particles.

_4

32 P.J. Kooyman, M. Slabova, V. Bosacek, J. Cejka, J. Rathousky, and A. Zukal,

Coll. Czech. Chem. Commun. 66 (2001) 555-566. The influence of pH on

the structure of templated mesoporous silicas prepared from sodium

metasilicate.

33 M.J. Verhoef, P.J. Kooyman, J.C. van der Waal, M.S. Rigutto, J.A. Peters, H.

van Bekkum, Chem. Mater. 13 (2001) 683-687. Partial transformation of

MCM-41 material into zeolites: formation of nanosized MFI type crystallites.

34 P.J. Kooyman, E.J.M. Hensen, A.M. de Jong, J.W. Niemantsverdriet, J.A.R. van

Veen, Catal. Lett. 74 (2001) 49-53. The observation of nanometer-sized

entities in sulphided Mo-based catalysts on various supports.

35 J. Rathousky, J. Cejka, P.J. Kooyman, M. Slabova and A. Zukal, SSSC 135,

Proc. 13th IZC, Montpellier, France, July 8-13, 2001. A06P20. Controlling

the assembly of silica mesoporous materials by varying the decrease in pH.

36 E. Toukoniitty, B. Secikova, N. Kumar, P. Mäki-Arvela, T. Salmi, J. Väyrynen,

T. Ollonqvist, E. Laine, P.J. Kooyman, and D.Y. Murzin, SSSC 135, Proc.

13th IZC, Montpellier, France, July 8-13, 2001. A23P25. Synthesis and

characterisation of mesoporous Pt-MCM-41and its application in

enantioselective hydrogenation of 1-phenyl-1,2-propanedione.

37 P.J. Kooyman, P. Waller, A.D. van Langeveld, C. Song, K. M. Reddy and J.A.R.

van Veen, Recent Research Reports, 13th IZC, Montpellier, France, July

8-13, 2001. 26-R-02. MCM-41 as a support for CoMoS hydrotreating

catalysts.

38 B. Lindlar, A. Kogelbauer, P.J. Kooyman, and R. Prins, Microporous and

Mesoporous Materials 44-45 (2001) 89-94. Synthesis of Large Pore Silica

and Silica-alumina with a Narrow Pore Size Distribution.

39 E. Toukoniitty, P. Mäki-Arvela, A. Kalantar-Neyestanaki, T. Salmi, R. Sjöholm,

R. Leino, E. Laine, P.J. Kooyman, T. Ollonqvist and J. Väyrynen, Appl.

Catal. A: General 216 (2001) 73-83. Batchwise and continuous

enantioselective hydrogenation of 1-phenyl-1,2-propanedione catalysed by

new Pt/SiO2 fibers.

40 P.J. Kooyman, E.J.M. Hensen, A.M. de Jong, J.W. Niemantsverdriet and J.A.R.

van Veen, Proc. Europacat V, Limerick, Ireland, September 2-7, 2001. 20-

P-17. The observation of nanometer-sized entities in sulphided Mo-based

catalysts on various supports.

41 F. Devred, B. Hoffer, P.J. Kooyman and H.W. Zandbergen, Proc. Europacat V,

Limerick, Ireland, September 2-7, 2001. 6-P-14. Raney-type nickel

catalysts: a HREM study.

42 B. Hoffer, F. Devred, A.D. van Langeveld, P.J. Kooyman, R.L.C Bonné, C.M.

Lok and J.A. Moulijn, Proc. Europacat V, Limerick, Ireland, September

2-7, 2001. 13-P-02. Activation behaviour of ex-situ presulfided Ni/Al2O3

catalysts for pyrolysis gasoline hydrogenation: temperature programmed

studies.

43 J. Hajek, E. Toukoniitty, P. Kacer, P. Mäki-Arvela, L. Cerveny, N. Kumar, D.

Yu. Murzin, T. Salmi, E. Laine, P.J. Kooyman, T. Ollonqvist and J. Väyrynen,

Proc. Europacat V, Limerick, Ireland, September 2-7, 2001. 16-P-12.

Preparation and properties of Ru-Sn sol-gel catalysts.

44 E. Toukoniitty, P. Mäki-Arvela, A. Kalantar-Neyestanaki, T. Salmi, D. Yu.

Murzin, E. Laine, P.J. Kooyman, T. Ollonqvist and J. Väyrynen, Proc.

Europacat V, Limerick, Ireland, September 2-7, 2001. 16-P-13. Transient

_5

studies in complex enantioselective hydrogenation - kinetics, regio- and

enantioselectivity.

45 N. Maxim, P.C.M.M. Magusin, P.J. Kooyman, J.H.M.C. van de Wolput, R.A.

van Santen and H.C.L. Abbenhuis, Chem. Mater. 13 (2001) 2958-2964.

Microporous Mg-Si-O and Al-Si-O materials derived from metal

silsesquioxanes.

46 R. Huq, L. Mercier and P.J. Kooyman, Chem. Mater. 13 (2001) 4512-4519.

Incorporation of cyclodextrin into mesostructured silica.

74 M. McInall, J. Scott, L. Mercier and P.J. Kooyman, Chem. Commun. (2001)

2282-2283. Super-microporous organic-integrated silica prepared by nonelectrostatic

surfactant.

2002

47 M.K. Oudenhuijzen, P.J. Kooyman, B. Tappel, J.A. van Bokhoven and D.C.

Koningsberger, J. Catal. 205 (2002) 135-146. Understanding the Influence of

the Pretreatment Procedure on Platinum Particle Size and Particle-Size

Distribution for SiO2 impregnated with [Pt2+(NH3)4](NO3-)2: a combination of

HRTEM, mass spectrometry and quick EXAFS.

48 Lu Gang, B.G. Anderson, J. van Grondelle, R.A. van Santen, W.J.H. van

Gennip, J.W. Niemansverdriet, P.J. Kooyman, A. Knoester and H.H.

Brongersma, J. Catal. 206 (2002) 60-70. Alumina-supported Cu-Ag catalysts

for ammonia oxidation at low temperature.

49 M. Sun, P.J. Kooyman, and R. Prins, J. Catal. 206 (2002) 368-375. A High-

Resolution Transmission Electron Microscopy Study of the Influence of

Fluorine on the Morphology of WS2 in Sulfided W/Al2O3 and NiW/Al2O3

catalysts.

50 B. W. Hoffer, F. Devred, P.J. Kooyman, A.D. van Langeveld, R.L.C. Bonné, C.

Griffiths, C.M. Lok and J.A. Moulijn, J. Catal. 209 (2002) 245-255.

Characterisation of ex-situ presulphided Ni/Al2O3 catalysts for pyrolysis

gasoline hydrogenation.

51 E. Prouzet, F. Cot, C. Boissière, P.J. Kooyman, and A. Larbot, J. Material.

Chem. 12 (2002) 1553-1556. Nanometric hollow spheres made of MSU-Xtype

mesoporous silica.

52 P.J. Kooyman, Second FEZA Conference, Book of Abstracts and Recent

Research Reports, Impact of zeolites and other porous materials on the

new technologies at the beginning of the new century. RRR 028. TEM/

HREM characterisation of Fe/ZSM-5.

54 F.R. van den Berg, M.W.J. Crajé, P.J. Kooyman, A.M. van der Kraan and J.W.

Geus, Appl. Catal. A: General 235 (2002) 217-224. Synthesis of Highly

Dispersed Zirconia-Supported Iron-Based Catalysts for Fischer-Tropsch

Synthesis.

55 J. Cejka, P.J. Kooyman, L. Vesela, J. Rathousky and A. Zukal, PCCP 4 (2002)

4823-4829. Post-synthesis thermal restructuring of organised mesoporous

alumina.

56 N. Maxim, A. Overweg, P.J. Kooyman, J.H.M.C. van Wolput, R.W.J.M.

Hanssen, R.A. van Santen and H.C.L. Abbenhuis, J. Phys. Chem. B 106

(2002) 2203-2209. Synthesis and characterisation of microporous Fe-Cr-Si-O

materials with tailored iron content from silsesquioxane precursors.

_6

57 P.J. Kooyman, J.G. Buglass, H.R. Reinhoudt, E.J.M. Hensen, A.D. van

Langeveld, H.W. Zandbergen and J.A.R. van Veen J. Phys. Chem. B 106

(2002) 11795-11799. Quasi in situ sequential sulphidation of CoMo/Al2O3

studied using High Resolution Electron Microscopy.

75 R.D. Vis, A. Mwowiec, P.J. Kooyman, K. Matsubara and D. Heymann,

Meteoritics and planetary science 37 (2002) 1391-1399. Microscopic search

for the carrier phase Q of the trapped planetary noble gases in Allende,

Leoville and Vigarano.

76 N. Maxim, A. Overweg, P.J. Kooyman, A. Nagy, R.A. van Santen and H.C.L.

Abbenhuis, J. Mater. Sci. 12 (2002) 3792-3798. Synthesis and

characterisation of microporous bimetallic Fe-Cr-Si-O materials derived from

silsesquioxane precursors.

 

2003

58 A.A. Battiston, J.H. Bitter, F.M.F. de Groot, A.R. Overweg, O. Stephan, J.A.

van Bokhoven, P.J. Kooyman, C. van der Spek, G. Vankó, and D.C.

Koningsberger, J. Catal. 213 (2003) 251-271. Evolution of Fe Species during

the synthesis of overexchanged Fe/ZSM5 obtained by chemical vapor

deposition of FeCl3.

59 C. Boissière, M.A.U. Martines, P.J. Kooyman, T.R. de Kruijff, A. Larbot and E.

Prouzet, Chem. Mater. 15 (2003) 460-463. Ultrafiltration membrane made

with mesoporous MSU-X silica.

60 F. Devred, B. Hoffer, W.G. Slooff, A.D. van Langeveld, P.J. Kooyman and H.W.

Zandbergen, Proceedings NCCC VI, Noordwijkerhout, The Netherlands,

March 10-12, 2003 p. 212. Raney-type nickel catalysts: an XRD and XPS

study.

61 L. Qu, W. Zhang, P.J. Kooyman, and R. Prins, J. Catal. 215 (2003) 7-13. MAS

NMR, TPR, and TEM studies of NiMo with alumina and silica-alumina

supports.

62 F. Devred, B.W. Hoffer, W.G. Slooff, P.J. Kooyman, A.D. van Langeveld, and

H.W. Zandbergen, Appl. Catal. A: General 244 (2003) 291-300. The genesis

of the active phase in Raney-type catalysts: the role of leaching parameters.

63 J. Cinibulk, P.J. Kooyman, Z. Vít and M. Zdrazil, Catal. Lett. 89 (2003)

147-152. Magnesia supported Mo, CoMo and NiMo sulfide catalysts prepared

by non-aqueous impregnation: parallel HDS/HDN of thiophene and pyridine

and TEM microstructure.

64 L.J. Simon, P.J. Kooyman, J.G. van Ommen and J.A. Lercher, Appl. Catal. A:

General 252 (2003) 283-293. Effect of Co and Ni on benzene hydrogenation

and sulfur tolerance of Pt/H-MOR.

65 P.J. Kooyman, P. Waller, A.D. van Langeveld, C. Song, K. Reddy and J.A.R.

van Veen, Catal. Lett. 90 (2003) 131-135. Stability of MCM-41 supported

CoMo hydrotreating catalysts.

66 E. Crezee, P.J. Kooyman, J. Kiersch, W.G. Sloof, G. Mul, F. Kapteijn and J.A.

Moulijn, Catal. Lett. 90 (2003) 181-186. Dispersion and distribution of

ruthenium on carbon-coated ceramic monolithic catalysts prepared by

impregnation.

67 B.W. Hoffer, E. Crezee, F. Devred, P.R.M. Mooijman, W.G. Sloof, P.J.

Kooyman, A.D. van Langeveld, F. Kapteijn and J.A. Moulijn, Appl. Catal. A:

_7

General 253 (2003) 437-452. The role of the active phase of Raney-type Ni

catalysts in the selective hydrogenation of D-glucose to D-sorbitol.

68 Q. Sun, P.J. Kooyman, J.G. Grossmann, P.H.H. Bomans, P.M. Frederik,

P.C.M.M. Magusin, T.P.M. Beelen, R.A. van Santen and N.A.J.M.

Sommerdijk, Adv. Mater. 15 (2003) 1097-1100. The formation of highly

monodisperse hollow silica spheres with multilamellar shell structure.

69 P.J. Kooyman, S. Helveg, and A. Boisen, Proceedings of the NVvM 2003

meeting in Papendal, Arnhem, Dec 11-12 2003. In situ TEM reduction of

supported Cu-Pt nanoparticles.

2004

70 E.J.M. Hensen, Q. Zhu, M.M.R.M. Hendrix, A.R. Overweg, P.J. Kooyman,

M.V. Sychev and R.A. van Santen, J. Catal. 221 (2004) 560-574. Effect of

high-temperature treatment on Fe/ZSM-5 prepared by chemical vapour

deposition of FeCl3. I. Physicochemical characterisation.

71 J. Rathousky, M. Zukalova, P.J. Kooyman and A. Zukal, J. Coll. Surf. A 241

(2004) 81-86. Synthesis and characterisation of colloidal MCM-41.

72 M.F. Ottaviani, A. Moscatelli, D. Desplantier-Giscard, F. Di Renzo, P.J.

Kooyman, B. Alonso and A. Galarneau, J. Phys. Chem. B 108 (2004)

12123-12129. Synthesis of micelle-templated silicas from

cetyltrimethylammonium bromide / 1,3,5-trimethylbenzene micelles.

73 V. Hulea, D. Brunel, A. Galarneau, F. Fajula, K. Philippot, B. Chaudret and P.J.

Kooyman, Proceedings 4th International Mesostructured Materials

Symposium, Cape Town, May 1-4 2004 P-71. Synthesis of well-dispersed

ruthenium nanoparticles inside mesoporous MCM-41 materials under mild

conditions.

77 N. van Landschoot, E.M. Kelder, P.J. Kooyman, C. Kwakernaak and J.

Schoonman, J. Power Sources 138 (2004) 262-270. Electrochemical

performance of Al2O3-coated Fe doped LiCoVO4.

2005

78 M.A.U. Martines, E. Yeong, M. Persin, A. Larbot, W.F. Voorhout, C.K.U.

Kübel, P.J. Kooyman and E. Prouzet, C. R. Chimie 8 (2005) 187-194.

Hexagonal mesoporous silica nanoparticles with large pores and a

hierarchical porosity tested for HPLC.

79 V. Hulea, D. Brunel, A. Galarneau, K. Philippot, B. Chaudret, P.J. Kooyman and

F. Fajula, MMM 79 (2005) 185-194. Synthesis of well-dispersed ruthenium

nanoparticles inside mesoporous MCM-41 materials under mild conditions.

80 J.B. Taboada, A.R. Overweg, I.W.C.E. Arends, P.J. Kooyman, and G. Mul, J.

Catal. 231 (2005) 56-66. Following the evolution of iron from framework to

extra-framework positions in isomorphously substituted [Fe,Al]MFI with 57Fe

Mössbauer spectroscopy.

81 E.A. de Graaf, G. Rothenberg, P.J. Kooyman, A. Andreini and A. Bliek, Appl.

Catal. A: General 287 (2005) 185-194. Pt0.02Sn0.003Mg0.06 on alumina: a

stable oxidative dehydrogenation catalyst.

82 G. Surendran, M.S. Tokumoto, E. Pena dos Santos, H. Remita, L. Ramos, P.J.

Kooyman, C.Valentim Santilli, C. Bourgaux, P. Dieudonné and E. Prouzet,

Chem. Mater. 17 (2005) 1505-1514. Highly swollen liquid crystals as new

reactors for the synthesis of nanomaterials.

_8

83 Y. Ji, A.J. van der Eerden, V. Koot, P.J. Kooyman, J.D. Meeldijk, B.M.

Weckhuysen and D.C. Koningsberger, J. Catal. 234 (2005) 376-384.

Influence of support ionicity on the hydrogen chemisorption of Pt particles

dispersed in Y zeolite. Consequences for Pt particle size determination using

the H/M method.

84 E.J.M. Hensen, Q. Zhu, R.A.J. Jansen, P.C.M.M. Magusin, P.J. Kooyman and

R.A. van Santen, J. Catal. 233 (2005) 123-135. Selective oxidation of benzene

to phenol with nitrous oxide over MFI zeolites. I. On the role of iron and

aluminum.

85 G. Surendran, G. Apostolescu, M.S. Tokumoto, E. Prouzet, L. Ramos, P.

Beaunier, P.J. Kooyman, A. Etcheberry and H. Remita, Small 1 (2005)

964-967. From self-assembly of platinum nanoparticles to nanostructured

materials.

86 J.B. Taboada, A.R. Overweg and P.J. Kooyman, Stud. Surf. Sci. Catal. 158

(2005) 27-34. Direct synthesis of mesoporous Fe-MFI zeolite.

87 U. Lafont, P.J. Kooyman, A. Galarneau, and F. Di Renzo, Stud. Surf. Sci.

Catal. 155 (2005) 355-366. Templated and non-templated routes to

mesoporous titanium dioxide.

88 A.M. Paulaime-van Donk, P.J. Kooyman and J.C. Jansen, Stud. Surf. Sci.

Catal. 158 (2005) 351-358. The introduction of carbon oligomers into the

framework of silicalite-1.

89 M.B. Thathagar, P.J. Kooyman, R. Boerleiden, E. Jansen, C.J. Elsevier and G.

Rothenberg, Adv. Synth. Catal. 137 (2005) 1965-1968. Pd nanoclusters in

Sonogashira cross-coupling: a true catalytic species?

90 S. van Donk, B. Weckhuysen, F. Kapteijn, P.J. Kooyman and E.J.M. Hensen,

Catal. Today 110 (2005) 189-190. Introduction (and editors of special issue).

2006

92 B. Toukoniitty, E. Toukoniitty, P. Mäki-Arvela, J.P. Mikkola, T. Salmi, D.Yu.

Murzin and P.J. Kooyman, Ultrasonics Sonochemistry 13 (2006) 68-75.

Effect of ultrasound in enantioselective hydrogenation of 1-phenyl-1,2-

propanedione: comparison of catalyst activation, solvents and supports.

93 A. Galarneau, J. Iapichella, K. Philippot, F. Di Renzo, P.J. Kooyman, O.

Terasaki and F. Fajula, Adv. Funct. Mater. 16 (2006) 1657-1667. Controlling

the morphology of mesostructured silicas by pseudomorphic transformation: a

route towards applications.

94 L. Laffont, C. Delacourt, P. Gibot, M.Y. Wu, P.J. Kooyman, C. Masquelier and

J.M. Tarascon, Chem. Mater. 18 (2006) 5520-5529. Study of the LiFePO4/

FePO4 two-phase system by high-resolution electron energy loss spectroscopy.

98 O. Muraza, E.V. Rebrov, T. Khimyak, B.F.G. Johnson, P.J. Kooyman, U. Lafont,

P.A. Albouy, M.H.J.M. de Croon and J.C. Schouten, Stud. Surf. Sci. Catal.

162 (2006) 167-174. Preparation and characterization of bimetallic catalysts

supported on mesoporous silica films.

2007

95 E.G. Vrieling, Q. Sun, M. Tian, P.J. Kooyman, W.W.C. Gieskes, R.A. van

Santen and N.A.J.M. Sommerdijk, PNAS 104 (2007) 10441-10446. Salinitydependent

diatom biosilicification implies an important role of external ionic

strength.

_9

96 J.B. Taboada, A.R. Overweg and P.J. Kooyman, Stud. Surf. Sci. Catal. 170

(2007) 355-362. Direct synthesis of mesoporous Fe-MFI zeolite.

2008

97 P.J. Kooyman and J.A.R. van Veen, Catalysis Today 130 (2008) 135–138. The

detrimental effect of exposure to air on supported MoS2.

99 O. Muraza, E.V. Rebrov, T. Khimyak, B.F.G. Johnson, P.J. Kooyman, U. Lafont,

P.A. Albouy, M.H.J.M. de Croon and J.C. Schouten, Chemical Engineering

Journal 135S (2008) S99–S103. Mesoporous silica films as catalyst support

for microstructured reactors: Preparation and characterization.

100 M. Mirdamadi-Esfahani, M. Mostafavi, B. Keita, L. Nadjo, P.J. Kooyman, A.

Etcheberry, M. Imperor and H. Remita, Gold Bulletin 41 (2008) 98-104. Au-

Fe system: application in electrocatalysis.

101 D. Ortiz de Zarate, F. Bouyer, H. Zschiedrich, P.J. Kooyman, P. Trens, J.

Iapichella, R. Durand, C. Guillem and E. Prouzet, Chem. Mater. 20 (2008)

1410-1420. Micromesoporous monolithic Al-MSU with a widely variable

content of aluminum leading to tunable acidity.

102 E. de Smit, I. Swart, J.F. Creemer, G.H. Hoveling, M.K. Gilles, T. Tyliszczak,

P.J. Kooyman, H.W. Zandbergen, C. Morin, B.M. Weckhuysen and F.M.F. de

Groot, Nature 456 (2008) 222-225. Nanoscale chemical imaging of a working

catalyst by scanning transmission X-ray microscopy.

2009

103 J.F. Creemer, S. Helveg, G.H. Hoveling, S. Ullmann, P.J. Kooyman, A.M.

Molenbroek, H.W. Zandbergen and P.M. Sarro, IEEE International

Conference on MEMS technical digest 22 (2009) 76-79. MEMS

nanoreactor for atomic-resolution microscopy of nanomaterials in their

working state.

104 S. Janbroers, T.R. de Kruijff, Q. Xu, P.J. Kooyman and H.W. Zandbergen,

Ultramicroscopy 109 (2009) 1105–1109. Preparation of carbon-free TEM

microgrids by metal sputtering.

105 M.A. Lélias, P.J. Kooyman, L. Mariey, L. Oliviero, A. Travert, J. van Gestel,

J.A.R. van Veen and F. Maugé, J. Catal. 267 (2009) 14-23. Effect of NTA

addition on the structure and activity of the active phase of cobaltmolybdenum

sulfide hydrotreating catalysts.

106 S. Janbroers, J.N. Louwen, H.W. Zandbergen and P.J. Kooyman, J. Catal. 268

(2009) 235-242. Insights into the nature of iron-based Fischer–Tropsch

catalysts from quasi in situ TEM-EELS and XRD.

113 Y. Li, Y. Guan, R.A. van Santen, P.J. Kooyman, I. Dugulan, C. Li and E.J.M.

Hensen, J. Phys. Chem. C 113 (2009) 21831–21839. Direct Hydrothermal

Synthesis of Iron-Containing Mesoporous Silica SBA-15: Potential as a

Support for Gold Nanoparticles.

2010

107 M. Mirdamadi-Esfahani, M. Mostafavi, B. Keita, L. Nadjo, P. Kooyman and H.

Remita, Gold Bull. 43 (2010) 49-56. Bimetallic Au-Pt nanoparticles

synthesized by radiolysis: Application in electro-catalysis.

_10

109 E. Talgorn, R.D. Abellon, P.J. Kooyman, J. Piris, T.J. Savenije, A. Goossens,

A.J. Houtepen and L.D. A. Siebbeles, ACS Nano 4 (2010) 1723–1731.

Supercrystals of CdSe Quantum Dots with High Charge Mobility and Efficient

Electron Transfer to TiO2.

110 J.F. Creemer, S. Helveg, P.J. Kooyman, A.M. Molenbroek, H.W. Zandbergen

and P.M. Sarro, J MEMS 19 (2010) 254-264. A MEMS Reactor for Atomic-

Scale Microscopy of Nanomaterials Under Industrially Relevant Conditions.

2011

108 B.M. Vogelaar, A.D. van Langeveld, P.J. Kooyman, C.M. Lok, R.L.C. Bonné

and J.A. Moulijn, Catal. Today 163 (2011) 20-26. Stability of metal

nanoparticles formed during reduction of alumina supported nickel and cobalt

catalysts.

111 S. Janbroers, P.A. Crozier, H.W. Zandbergen and P.J. Kooyman, Appl. Catal.

B: Environm 102 (2011) 521-527. A model study on the carburization

process of iron-based Fischer–Tropsch catalysts using in situ TEM–EELS.

112 Contribution to book: Chemie: voor een veilig en duurzaam leefklimaat -

interviews met wetenschappers over toepassingen en mogelijkheden, door

Emma van Laar in opdracht van VNCI/NWO.

2013

114 A.F. Pérez-Cadenas, C.H. Ros, S. Morales-Torres, M. Pérez-Cadenas, P.J.

Kooyman, C. Moreno-Castilla and F. Kapteijn, Carbon 56 (2013) 324-311.

Metal-doped carbon xerogels for the electro-catalytic conversion of CO2 to

hydrocarbons.

115 S. Vendelbo, P.J. Kooyman, J.F. Creemer, B. Morana, L. Mele, P. Dona, B.

Nelissen and S. Helveg, Ultramicroscopy 133 (2013) 72-79. Method for local

temperature measurement in a nanoreactor for in situ high-resolution electron

microscopy.

2014

116 E. Skupien, R.J. Berger, V.P. Santos, J. Gascon, M. Makkee, M.T. Kreutzer, P.J.

Kooyman, J.A. Moulijn and F. Kapteijn. Catalysts 4 (2014) 89-115. Inhibition

of Gold Based Catalyst in Benzyl Alcohol Oxidation: Understanding and

Remediation.

117 S. Vendelbo, C.F. Elkjaer, H. Falsig, I. Puspitasari, P. Dona, L. Mele, B.

Morana, R. van Rijn, B. Nelissen, J.F. Creemer, P.J. Kooyman and S. Helveg,

Nature Materials 13 (2014) 884-890. Atomic-scale visualisation of Pt

nanoparticles catalysing the oscillatory CO oxidation.

2015

118 L. van Haandel, G.M. Bremmer, P.J. Kooyman, J.A.R. van Veen, T. Weber,

E.J.M. Hensen. ACS Catalysis 5 (2015) 7276-7287. Structure−Activity

Correlations in Hydrodesulfurization Reactions over Ni-Promoted

MoxW(1−x)S2/Al2O3 Catalysts.

_11

2016

119 B.A. van Driel, P.J. Kooyman, K.J. van den Berg, A. Schmidt-Ott, J.Dik.

Microchemical Journal. A quick assessment of the photocatalytic activity of

TiO2 pigments - From lab to conservation studio!

Accepted: